Ni-Catalyzed direct 1,4-difunctionalization of [60]fullerene with benzyl bromides.
نویسندگان
چکیده
A new Ni-catalyzed direct 1,4-difunctionalization of [60]fullerene with various benzyl bromides has been developed. The use of a DMSO additive combined with a nickel catalyst is indispensable for the formation of 1,4-dibenzyl fullerenes with a variety of functional groups. The reaction proceeds through the formation of a fullerene monoradical species.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 29 شماره
صفحات -
تاریخ انتشار 2015